High Fives: Reese Witherspoon

Reese Witherspoon rarely stumbles, fashion-wise, but her structural black-and-white cocktail dress by Narciso Rodriguez was a particularly winning number at Avon's "Champions Who Change Women's Lives" event the other night.

Witherspoon is actually an Avon ambassador -- and even has her own perfume, "Bloom by Reese Witherspoon" -- and given all that, we're especially impressed that she steered clear of the "women at women's events wear pink or some bright and cheery color" rut. This Narciso Rodriguez dress flatters all her best features -- her athletic shoulders and tiny waist -- and the contrasting fabric in the skirt gives the whole dress a more couture-inspired effect. Finally, a loose, unfussy hairdo is the perfect complement to a fashion-forward piece like this one.

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